Fabrication and Characterization of Novel Pb(II) and Cr(III) Ion Selective and Sensitive Electrodes

Naheed Azam; Seema I. Habib; Muzdan Abdul Wahab Madoo

doi:10.24018/ejchem.2022.3.4.119

Naheed Azam

Seema I. Habib

Muzdan Abdul Wahab Madoo

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The Lead - Ion Selective Electrode (Pb-ISE) and Chromium-Ion electrode (Cr-ISE) is a method for the analytical determination of Pb(II) and Cr(III) in natural matrices. The ISEs are very sensitive, selective, and inexpensive analytical tools that can be applied to determine Pb(II) and Cr(III) in soil samples due to relatively high limits of detection. In the present work, we examined the possibility of using solid contact ISEs in soil analysis, combined with a simplified extraction method based on dilute HNO₃ that can be carried out at the field site. The Ionic strength of lead and Chromium is measured by using The Pb-ISE and Cr-ISE were fabricated and their characteristics were studied separately and the Ionic strength of Pb(II) and Cr(III) was measured by using them, the results were found to be quite satisfactory.

Keywords: Analytical Technique, Cr(III) ISE, Pb(II) ISE, Soil Samples.

Kim HJ, Sudduth KA, Hummel JW, Drummond ST. Validation Testing of a Soil Macronutrient Sensing System. American Society of Agricultural & Biological Engineers, 2013. | Google Scholar
Kim HJ, Sudduth KA, Hummel JW. Soil Macronutrients Sensing for Precision Agriculture, Journal of Environmental Monitoring, 2009; 11(10). | Google Scholar
Xue F, Xia YYM, Faheem M. Electro-Kinetic Remediation of Chromium Contaminated Soil by a Three Dimensional Electrode Coupled with a Permeable Reactive Barrier. RSC Advances, 2017; 7(86). | Google Scholar
Reddy KR, Reddy SC. Effects of Initial Form of Chromium on Electro Kinetic Remediation in Clays. Advances in Environmental Research, 2003; 353–365. | Google Scholar
Onweremadu E, Uhuegbu A. Chromium (III) in Relation to Soil Properties and Bioaccessibility in Soils Polluted by Animal Wastes. Nature and Science of Sleep, 2007;5(2). | Google Scholar
Villalobos-Neri EE, Garcia UP, Hexavalent Chromium Reduction at the Polypyrrole Coated 304- Stainless Steel Electrode in a Filter Press Type Reactor, Int. J. Electrochem. Sci. 16(2021). | Google Scholar
Lie J, Sun Y. A New Electrochemical detection technique for organic matter content in Ecological soils, Orginal Research article, 2021. | Google Scholar
March G, Nguyen DZT. Modified electrodes used for Electrochemical Detection of Metal Ions in Environmental Analysis. BenoitPiro, 2015. | Google Scholar
Kumar UN, Ramvath JN, Ghosh S. Chromium Oxy nitride as durable electrode material for symmetric supercapacitors. Batteries & Supercaps, 2020; 3: 780-788. | Google Scholar
Jin Kim H, Motavalli P. Simultaneous analysis of soil macronutrients using Ions selective electrodes. Soil Science society of America Journal, 2007; 71(6). | Google Scholar
Surkar PK, Karwankar AR. Automatic testing of soil samples using ion selective electrodes (ISEs), International conference, 2016. | Google Scholar
Abad SQ, Beone GM. Quantification of Cr(VI) in soil samples from a contaminated area in northern Italy by isotope dilution mass spectrometry, Environmental Science & Pollution Research, 2015. | Google Scholar
Asfaw TB, Tadesse TM, Ewnetie AM. Determination of Total Chromium and Chromium Species in Kombolcha Tannery Wastewater, Surrounding Soil, and Lettuce Plant Samples, South Wollo, Ethiopia. Advances in Chemistry, 2017: 1–7. https://doi.org/10.1155/2017/6191050. | Google Scholar
V, Gupta V. K. Sing, Sameena M & B. G., Analytical Chemical Actuators 566, 5-10, 2006. | Google Scholar
B, Ardakani MM, Kashni MK, Salavati M. Sensors and Actuators. Chemical, 2005; 107: 1, 438-445. | Google Scholar

How to Cite

Azam, N., Habib, S. I., & Madoo, M. A. W. (2022). Fabrication and Characterization of Novel Pb(II) and Cr(III) Ion Selective and Sensitive Electrodes. European Journal of Advanced Chemistry Research, 3(4), 16–19. https://doi.org/10.24018/ejchem.2022.3.4.119