Remove of Humic Acid From Water Using Magnetite Nanoparticles
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Synthesis, characterization and application of iron oxide nanoparticles have received much attention in recent years due to their interesting chemical and physics properties. Magnetite (Fe3O4) nanoparticles were synthesed by chemical co-precipitation and characterized using X ray diffraction (XDR), Fourier transmission spectroscopy (FT-IR), dynamic light scattering and (DLS). Fe3O4 nanoparticles were successfully removed humic acid (HA) from water. The influence of pH, contact time, adsorbent nanoparticle doses and HA concentrations were analyzed. Maximum HA removal occurred at pH 6 (89.63%), 40 mg.L-1 of Magnetite (88.8%), 0.03g of HA (96.64%) and contact time of 20 min (94.37%). Sorption data fit pseudo-second order kinetics, indicated a chemical adsorption process. The Langmuir, Freundlich and Temkin adsorption isotherm models were applied to describe equilibrium data. Adsorption of HA on magnetite nanoparticles was well described by Temkin model. The maximum adsorption capacity was 128.23 mg.g-1. Fe3O4 nanoparticles were promising potential adsorbents for HA removal from water.
References
-
H. El Ghandoor, H. M. Zidan, M. Khalil, M. I. M. Ismail, Synthesis and some physical properties of magnetite (Fe3O4) nanoparticles, Int. J. Electrochem. Sci. 2012 (7), 5734-5745.
Google Scholar
1
-
L. Blaney, Magnetite (Fe3O4): Properties, Synthesis, and Applications, Lehigh Review. 2007 (15), 1-50.
Google Scholar
2
-
M. C. Mascolo, Y. Pei, T. A. Ring, Room temperature co-precipitation synthesis of magnetite nanoparticles in a large pH window with different bases, Materials. 2013 (6), 5549-5567.
Google Scholar
3
-
O. M. Lemine, K. Omri, B. Zhang, Sol gel synthesis of 8nm magnetite (Fe3O4) nanoparticles and their magnetic properties, Superlattices and Microstructures. 2012 (52), 793-799.
Google Scholar
4
-
X. Sun, C. Zheng, F. Zhang, Y. Yang, G. Wu, A. Yu, N. Guang, Size-controlled synthesis of magnetite (Fe3O4) nanoparticles coated with glucose and gluconic acid a single Fe (III) precursor by a sucrose bifunctional hydrothermal method, J. Phys. Chem. C. 2009 (36), 16002-16008.
Google Scholar
5
-
S. F. Chin, S. C. Pang, C. H. Tan, Green Synthesis Nanoparticles (via thermal Decomposition Method) with controllable Size and Shape, Mater. Environ. Sci. 2011 (3), 299-302.
Google Scholar
6
-
B. Saha. S. Das, J. Saikia, G. Das, Preferential and Enhanced Adsorption of Different Dyes on Iron Oxide: A comparative Study, J. Phys. Chem. C. 2011 (115), 8024-8033.
Google Scholar
7
-
A. Ali, H. Zafar, M. Zia, Synthesis, characterization, applications and challenges of iron oxide nanoparticles, Nanotechnol. Sci. Appl. 2016 (9), 49-67.
Google Scholar
8
-
SH. Chen, Z. Yin, SL. Luo. CT. Au, X. J. Li, Preparation of magnetite Fe3O4/SiO2/Bi2WO6 microspheres and their application in photocatalysis, Materials Research Bulletin. 2013 (48), 725-729.
Google Scholar
9
-
S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, L. Vander, R. N. Muller, Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations and biological applications, Chem. Rev. 2008 (108), 2064-2110.
Google Scholar
10
-
S. Rajput, C. U Pittman, D. Mohan, Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water, J. of col. and Inter. Sci. 2016 (468), 334-346.
Google Scholar
11
-
H. Wang, A. A. Keller, K. K. Clark, Natural organic matter removal by adsorption onto magnetic permanently confined micelle arrays. Journal of Hazardous materials, 2011 (194), 156-161.
Google Scholar
12
-
L. Liang, Adsorption and desorption of humic acid and fulvic acids on SiO2 particles at nano-and micro-scales, Colloids and surfaces, A 2011 (384), 126-130.
Google Scholar
13
-
K. Ghosh, M. Schnitzer, Macromolecular structures of humic substances Soil Science. 1980 (129), 266-276.
Google Scholar
14
-
Q. Tao, Z. Xu, J. Wang, F. Liu H. Wan, S. Zheng, Adsorption of humic acid to aminopropyl functionalized SBA-15, Microporous and Mesoporous Materials, 2010 (131), 177-185.
Google Scholar
15
-
H. Gallard, U. V. Gunten, Chlorination of natural organic matter: kinetics of chlorination and of THM formation, Water Research, 2002 (36), 65-74.
Google Scholar
16
-
A. Matilainen, M. Vepsalaienen, M. Sillanpaa, Natural organic matter removal by coagulation during drinking water treatment: a review, Advances in colloids interface Science, 2010 (159), 189-197.
Google Scholar
17
-
B. Bolto, D. Dixon, R. Eldridge, Ion exchange for the removal of natural organic matter, React. Funct. Poly. 2004 (60), 171-182.
Google Scholar
18
-
I. Sutzkover-Gutman, D. Hasson, R. Semiat, humic substances fouling in ultrafiltration processes, Dessalination, 2010 (261), 218-231.
Google Scholar
19
-
R. Lamsal, Comparison of advanced oxidation processes for the removal of organic natural matter, Water Research. 2011 (45), 3263-3269.
Google Scholar
20
-
S. Wang, T. Terdkiatburana, M. O. Tadé, Single of co-adsorption of heavy metals and humic acid on fly ash, Separat. Purif. Technol. 2008 (58), 353-358.
Google Scholar
21
-
C. Dong, W. Chen, C. Liu, Preparation of novel chitosan nanoparticles and its application for removal humic from aqueous solution, Appl. Surf. Sci. 2014 (292), 1067-1076.
Google Scholar
22
-
K. Gul, E. Gunes, Comparison of acid red 114 dye adsorption by Fe3O4 and Fe3O4 impregnated rice husk ash, J. of Nanomaterials. 2016, 1-11.
Google Scholar
23
-
P. L. Hariani, M. Faizal, R. Ridwan, M. Marsi, D. Setiabudidaya, Synthesis and properties of Fe3O4 nanoparticles by co-precpitation method to removal procion dye, Int. J. of Environ. Sci. and Devel. 2013 (4), 336-340.
Google Scholar
24
-
W.S. Wan Ngah, M.A.K.M. Hanafiah, S.S. Yong, Adsorption of humic acid from aqueous solutions on crosslinked chitosan-epichlorohydrin beads: kinetics and isotherm studies, Colloids and Surfaces B. 2008 (65), 18-24.
Google Scholar
25
-
K.V. Kumar, S. Sivanesan, Selection of optimum sorption kinetics: comparison of linear and non-linear method, Journal of Hazardous Materials. 2006 (134), 277-279.
Google Scholar
26
-
C. Sheindorf, M. Rebhun, M. Sheintuch, A Freundlich-type multicomponent isotherm, J. Col. Inter. Sci. 1981 (79), 136-142.
Google Scholar
27
-
Y. Tang, H. Guo, L. Ciao, S. Yu, Synthesis of reduced graphene oxide/magnetite composites and investigation of their adsorption performance of fluoroquinolone antibiotics, Colloids and Surfaces A: Physicochem. Eng. Aspects. 2013 (424), 74–80.
Google Scholar
28
-
T. Madrakian, A. Afkhami, M. Ahmadi, Adsorption and kinetic studies of seven different organic dyes onto magnetite nanoparticles loaded tea waste and removal of them from wastewater samples, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2012 (99), 102–109.
Google Scholar
29
-
R.R. Sheha, E. Metwally, Equilibrium isotherm modeling of cesium adsorption onto magnetic materials, Journal of Hazardous Materials. 2007 (143), 354–361.
Google Scholar
30
-
S. Y. Yoon, C. G. Lee, J. A. Park, Kinetic, equilibrium and thermodynamic studies for phosphate adsorption to magnetic iron oxide nanoparticles, Chemical Engineering Journal. 2014 (236), 341-347.
Google Scholar
31
-
B. Tanhaei, A. Ayati. M. Lahtinen, Preparation and characterization of a novel chitosan/Al2O3/magnetite nanoparticles composite adsorbent for kinetic, thermodynamic and isotherm studies of Methyl Orange adsorption, Chemical Engineering Journal. 2015 (259), 1-10.
Google Scholar
32
-
A. Ben Dekhil, M. Smiri, A. Hafiane, Kinectic, thermodynamic and structural study of the biosorption of lead and cadmium by red macroalga (Cermamium virgatum), Journal of the Tunisian chemical society. 2017 (19), 381-390.
Google Scholar
33
-
S. Chatterjee, S. H. Woo, The removal of nitrate from aqueous solutions by chitosan hydrogel beads. J. Hazard. Mater., 2009 (164) 1012-1018.
Google Scholar
34
-
M. Alkan, Ö. Demirbaş, S. Çelikçapa, M. Doğan,, Sorption of acid red 57 from aqueous solution onto sepiolite. J. Hazard. Mater., 2004 (B116) 135-145.
Google Scholar
35